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Molality Calculator

Pick a mode, enter the known values, and the calculator returns molality, moles, or kg solvent using m = moles solute / kg solvent. Optionally enter solute as grams plus molar mass.

Solve for

Solute input

mol

Unit

Molality vs molarity

Molality (m) uses moles of solute per kilogram of solvent, a mass-based unit that does not change with temperature. Molarity (M) uses moles per liter of solution, which is volume-based and shifts with temperature as the solution expands or contracts. They are not interchangeable.

Result

Molality

0.5 mol/kg (m)

Formulam = moles solute / kg solvent = 0.5 / 1 = 0.5 mol/kg

Molality is preferred for colligative properties like boiling-point elevation and freezing-point depression, which depend on the solvent mass rather than the solution volume.

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Examples

0.5 mol solute in 1 kg solvent

= 0.5 m

29.22 g NaCl in 1 kg water (M=58.44)

≈ 0.5 m

Target 0.25 m with 0.1 mol solute

needs 0.4 kg solvent

2 m molality x 0.5 kg solvent

= 1 mol solute

How it works

Molality is a single-formula relation between moles of solute and mass of solvent. Solve for any of the three given the other two.

Molality · m = moles solute / kg solvent

Solute from grams · n = mass (g) / molar mass (g/mol)

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Frequently asked questions

Molality (m) is concentration measured in moles of solute per kilogram of solvent (mol/kg). A 1 m solution has 1 mole of solute dissolved in 1 kilogram of solvent (not solution).

Molarity (M) is moles per liter of solution and is volume-based. Molality is moles per kilogram of solvent and is mass-based. Molality does not change with temperature, while molarity does because the solution volume expands or contracts.

For colligative properties (boiling-point elevation, freezing-point depression, vapor-pressure lowering, osmotic considerations in some contexts), use molality. For most other intro chemistry problems, molarity is more common.

Molality uses only the solvent's mass. That makes the unit temperature-independent and decouples it from solute-driven volume changes. Molarity, by contrast, depends on the total solution volume.

Yes. Switch the solute input to 'Grams + molar mass'. The calculator converts grams to moles using n = m / M, then plugs into the molality formula.

Molality in mol/kg, also written 'm' (lowercase italic in formal notation). 1 m solution is read as 'one molal' to avoid confusion with 1 M (one molar).